Recent Advances in Electrochemical Carboxylation with CO2,Accounts of Chemical Research

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Recent Advances in Electrochemical Carboxylation with CO2
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2024-09-03 , DOI: 10.1021/acs.accounts.4c00417
Guo-Quan Sun ₁ , Li-Li Liao ₁ , Chuan-Kun Ran ₁ , Jian-Heng Ye ₁ , Da-Gang Yu ₁

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Carbon dioxide (CO₂) is recognized as a greenhouse gas and a common waste product. Simultaneously, it serves as an advantageous and commercially available C1 building block to generate valuable chemicals. Particularly, carboxylation with CO₂ is considered a significant method for the direct and sustainable production of important carboxylic acids. However, the utilization of CO₂ is challenging owing to its thermodynamic stability and kinetic inertness. Recently, organic electrosynthesis has emerged as a promising approach that utilizes electrons or holes as environmentally friendly redox reagents to produce reactive intermediates in a controlled and selective manner. This technique holds great potential for the CO₂ utilization.

中文翻译：

CO2 电化学羧化的最新进展

二氧化碳 (CO ₂ ) 被认为是一种温室气体和一种常见的废物。同时，它还可以作为一种有利且可商用的 C1 构建模块来生产有价值的化学品。特别地，用CO ₂进行羧化被认为是直接和可持续生产重要羧酸的重要方法。然而，由于CO ₂的热力学稳定性和动力学惰性，其利用具有挑战性。最近，有机电合成已成为一种有前途的方法，它利用电子或空穴作为环境友好的氧化还原试剂，以受控和选择性的方式生产反应中间体。该技术对于CO _{2 的}利用具有巨大的潜力。

更新日期：2024-09-03

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