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Efficient earth-abundant copper photocatalysis enabled by metal-arene interaction
Chem ( IF 19.1 ) Pub Date : 2024-08-29 , DOI: 10.1016/j.chempr.2024.08.006
Chong Deng , Wenliang Huang

In this issue of Chem, Che et al. report a dinuclear copper(I) complex as an air-stable, efficient photocatalyst for C–C coupling reactions with unactivated aryl/alkyl halides. The photoinduced metal-metal-to-ligand charge transfer excited state is capable of cleaving C–X bonds via halogen-atom transfer, while Cu-arene interaction is revealed to play a key role in enabling this photocatalysis.

中文翻译:


金属-芳烃相互作用实现地球上丰富的高效铜光催化作用



在本期《Chem》中,Che 等人。报告了一种双核铜(I)络合物作为空气稳定、高效的光催化剂,用于与未活化的芳基/烷基卤化物的 C-C 偶联反应。光诱导的金属-金属-配体电荷转移激发态能够通过卤素原子转移裂解C-X键,而Cu-芳烃相互作用被证明在实现这种光催化作用中发挥着关键作用。
更新日期:2024-08-29
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