Optical Review ( IF 1.1 ) Pub Date : 2024-08-23 , DOI: 10.1007/s10043-024-00911-6 Shengyi Liu , Duan Gao , Li Wang , Wenbin Song , Zhiliang Zhang , Peilin Du , Ying Zhu , Peijia Xiao , Qi Zhang
BaGeTeO6: Nd3+/Yb3+/Ho3+ green up-conversion phosphors were synthesized using the high-temperature solid-state reaction method. The optimal doping concentrations for the three dopant ions Nd3+, Yb3+, and Ho3+ were determined to be 1 mol%, 6 mol%, and 0.8 mol%, respectively, through the method of controlling variables. By analyzing the dependence of the up-conversion luminescence intensity on the pump current of the 980 nm laser, it was found that the green and red up-conversion emissions of Ho3+ ions under 980 nm laser excitation were both two-photon processes. Furthermore, the influence of temperature on the up-conversion luminescent properties of BaGeTeO6: Nd3+/Yb3+/Ho3+ green up-conversion phosphors under 980 nm laser excitation was investigated, and the temperature sensing properties of Ho3+ ions were discussed. The results indicated that, at room temperature and higher temperatures, both the red and green up-conversion emissions of the sample were two-photon processes. Within the range of excitation current used in the experiment, the ratio of red to green up-conversion luminescence intensity of Ho3+ ions was independent of the laser excitation current but correlated with the sample temperature. In the temperature range of 303–723 K, the ratio of red to green up-conversion luminescence intensity of Ho3+ ions exhibited a nonlinear relationship with temperature. Comparing the temperature sensing sensitivity of Ho3+ in different matrices, the results indicated that the sample possessed high temperature sensing sensitivity.
中文翻译:
Yb3+/Nd3+/Ho3+三重掺杂BaGeTeO6上转换荧光粉在980 nm激发下的发光特性和温度特性
采用高温固相反应法合成了BaGeTeO 6 :Nd 3+ /Yb 3+ /Ho 3+绿色上转换荧光粉。通过控制变量的方法确定了Nd 3+ 、Yb 3+和Ho 3+三种掺杂离子的最佳掺杂浓度分别为1 mol%、6 mol%和0.8 mol%。通过分析上转换发光强度对980 nm激光器泵浦电流的依赖性,发现Ho 3+离子在980 nm激光激发下的绿光和红光上转换发射均为双光子过程。进一步研究了温度对BaGeTeO 6 : Nd 3+ /Yb 3+ /Ho 3+绿色上转换荧光粉在980 nm激光激发下上转换发光性能的影响,以及Ho 3+的温度传感性能离子进行了讨论。结果表明,在室温和更高温度下,样品的红色和绿色上转换发射都是双光子过程。在实验所用的激发电流范围内,Ho 3+离子的红绿上转换发光强度比值与激光激发电流无关,但与样品温度相关。在303~723 K温度范围内,Ho 3+离子红绿上转换发光强度比与温度呈现非线性关系。 比较Ho 3+在不同基体中的感温灵敏度,结果表明该样品具有较高的感温灵敏度。