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Metal–organic frameworks for organic transformations by photocatalysis and photothermal catalysis
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2024-08-20 , DOI: 10.1039/d4cs00095a Hong-Guang Jin 1 , Peng-Cheng Zhao 1 , Yunyang Qian 2 , Juan-Ding Xiao 3 , Zi-Sheng Chao 1 , Hai-Long Jiang 2
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2024-08-20 , DOI: 10.1039/d4cs00095a Hong-Guang Jin 1 , Peng-Cheng Zhao 1 , Yunyang Qian 2 , Juan-Ding Xiao 3 , Zi-Sheng Chao 1 , Hai-Long Jiang 2
Affiliation
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Organic transformation by light-driven catalysis, especially, photocatalysis and photothermal catalysis, denoted as photo(thermal) catalysis, is an efficient, green, and economical route to produce value-added compounds. In recent years, owing to their diverse structure types, tunable pore sizes, and abundant active sites, metal–organic framework (MOF)-based photo(thermal) catalysis has attracted broad interest in organic transformations. In this review, we provide a comprehensive and systematic overview of MOF-based photo(thermal) catalysis for organic transformations. First, the general mechanisms, unique advantages, and strategies to improve the performance of MOFs in photo(thermal) catalysis are discussed. Then, outstanding examples of organic transformations over MOF-based photo(thermal) catalysis are introduced according to the reaction type. In addition, several representative advanced characterization techniques used for revealing the charge reaction kinetics and reaction intermediates of MOF-based organic transformations by photo(thermal) catalysis are presented. Finally, the prospects and challenges in this field are proposed. This review aims to inspire the rational design and development of MOF-based materials with improved performance in organic transformations by photocatalysis and photothermal catalysis.
中文翻译：
光催化和光热催化有机转化的金属有机框架
光催化有机转化，特别是光催化和光热催化，简称光（热）催化，是一种高效、绿色、经济的生产增值化合物的途径。近年来，由于其多样化的结构类型、可调的孔径和丰富的活性位点，基于金属有机骨架（MOF）的光（热）催化引起了有机转化领域的广泛兴趣。在这篇综述中，我们对基于 MOF 的有机转化光（热）催化进行了全面、系统的概述。首先，讨论了 MOFs 光（热）催化性能的一般机制、独特优势和提高策略。然后，根据反应类型介绍了基于MOF的光（热）催化有机转化的突出例子。此外，还介绍了几种具有代表性的先进表征技术，用于揭示光（热）催化下 MOF 基有机转化的电荷反应动力学和反应中间体。最后提出了该领域的前景和挑战。本综述旨在启发合理设计和开发基于 MOF 的材料，通过光催化和光热催化提高有机转化性能。
更新日期：2024-08-22
中文翻译：
光催化和光热催化有机转化的金属有机框架
光催化有机转化，特别是光催化和光热催化，简称光（热）催化，是一种高效、绿色、经济的生产增值化合物的途径。近年来，由于其多样化的结构类型、可调的孔径和丰富的活性位点，基于金属有机骨架（MOF）的光（热）催化引起了有机转化领域的广泛兴趣。在这篇综述中，我们对基于 MOF 的有机转化光（热）催化进行了全面、系统的概述。首先，讨论了 MOFs 光（热）催化性能的一般机制、独特优势和提高策略。然后，根据反应类型介绍了基于MOF的光（热）催化有机转化的突出例子。此外，还介绍了几种具有代表性的先进表征技术，用于揭示光（热）催化下 MOF 基有机转化的电荷反应动力学和反应中间体。最后提出了该领域的前景和挑战。本综述旨在启发合理设计和开发基于 MOF 的材料，通过光催化和光热催化提高有机转化性能。
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