Interfacial chemistry in multivalent aqueous batteries: fundamentals, challenges, and advances,Chemical Society Reviews

当前位置： X-MOL 学术 › Chem. Soc. Rev. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Interfacial chemistry in multivalent aqueous batteries: fundamentals, challenges, and advances
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2024-08-19 , DOI: 10.1039/d4cs00474d
Zhengyu Ju ₁ , Tianrui Zheng ₁ , Bowen Zhang ₁ , Guihua Yu ₁

Affiliation

As one of the most promising electrochemical energy storage systems, aqueous batteries are attracting great interest due to their advantages of high safety, high sustainability, and low costs when compared with commercial lithium-ion batteries, showing great promise for grid-scale energy storage. This invited tutorial review aims to provide universal design principles to address the critical challenges at the electrode–electrolyte interfaces faced by various multivalent aqueous battery systems. Specifically, deposition regulation, ion flux homogenization, and solvation chemistry modulation are proposed as the key principles to tune the inter-component interactions in aqueous batteries, with corresponding interfacial design strategies and their underlying working mechanisms illustrated. In the end, we present a critical analysis on the remaining obstacles necessitated to overcome for the use of aqueous batteries under different practical conditions and provide future prospects towards further advancement of sustainable aqueous energy storage systems with high energy and long durability.

中文翻译：

多价水系电池中的界面化学：基本原理、挑战和进展

作为最有前途的电化学储能系统之一，水系电池因其与商用锂离子电池相比具有高安全性、高可持续性和低成本等优势而受到广泛关注，在电网规模储能方面显示出巨大的前景。本特邀教程回顾旨在提供通用设计原则，以解决各种多价水性电池系统在电极-电解质界面处面临的关键挑战。具体来说，沉积调节、离子通量均质化和溶剂化化学调制是调节水系电池中组分间相互作用的关键原则，并说明了相应的界面设计策略及其基本工作机制。最后，我们对在不同实际条件下使用水系电池需要克服的剩余障碍进行了批判性分析，并为进一步发展具有高能量和长寿命的可持续水系储能系统提供了未来前景。

更新日期：2024-08-19

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南