Photochemical α-amination of carbonyl groups with iodinanes,Chemical Communications

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Photochemical α-amination of carbonyl groups with iodinanes
Chemical Communications ( IF 4.3 ) Pub Date : 2024-08-15 , DOI: 10.1039/d4cc03564j
Suyuan He ₁ , Boya Feng ₁ , Yiben Tang ₁ , Ruiping Chen ₁ , Yujing Guo ₁ , Rene M Koenigs ₁

Affiliation

We report on a photochemical reaction of silyl enol ethers with iminoiodinanes. This aza Rubottom reaction provides a direct access towards α-amino carbonyl compounds under catalyst free reaction conditions with light as the sole source of energy. Control experiments suggest the participation of triplet nitrene intermediates.

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