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Study on structural and optical properties of Tb3+ co-doped Au glasses for green optical application
Radiation Physics and Chemistry ( IF 2.8 ) Pub Date : 2024-07-16 , DOI: 10.1016/j.radphyschem.2024.112055
P. Mangthong , N. Srisittipokakun , R. Rajaramakrishna , N. Phuphathanaphong , P. Kanjanaboos , N. Intachai , S. Kothan , J. Kaewkhao

This report investigates the structure and optical properties of Tb3+ co-doped Au glasses, with a focus on their applicability in green luminescent optical behavior. The study of Tb3+ co-doping in the presence of Au nanoparticles (AuNPs) within glass matrices. The starting materials include SiO2, Al2O3, B2O3, CaO, Sb2O3, Na2O, K2O, SnO2, SeO2, Tb2O3, and AuNPs. Glass fabrication employs the conventional melt quenching technique, followed by comprehensive characterization of physical, optical, luminescence, and structural properties. The density values reported for the glass, ranged from 2.8269 to 2.8359 g/cm3, molar volume was 26.3382 to 26.2591 cm3/mol, and refractive index was 1.5438–1.5526. The absorption spectra consist of three absorption bands that are located at 524, 1894, and 2178 nm and are assigned to 7F65D4, 7F67F0,1,2, and 7F67F3, respectively. Photoluminescence (PL) and radioluminescence (RL) show similar trend and the optical properties are scrutinized using a spectrofluorometer. Size of the nanoparticle was evaluated and show around 8–16 nm and interplanar distance showing 2.1 Å. This study underscores the potential of Tb3+ and Au co-doped materials as promising for green optical applications.

中文翻译:


绿色光学用Tb3+共掺Au玻璃的结构和光学性能研究



本报告研究了 Tb3+ 共掺杂金玻璃的结构和光学性质,重点关注其在绿光发光光学行为中的适用性。在玻璃基质中存在金纳米粒子 (AuNP) 的情况下 Tb3+ 共掺杂的研究。起始材料包括 SiO2、Al2O3、B2O3、CaO、Sb2O3、Na2O、K2O、SnO2、SeO2、Tb2O3 和 AuNP。玻璃制造采用传统的熔融淬火技术,然后对物理、光学、发光和结构特性进行综合表征。报告的玻璃密度值范围为 2.8269 至 2.8359 g/cm3,摩尔体积为 26.3382 至 26.2591 cm3/mol,折射率为 1.5438–1.5526。吸收光谱由位于 524、1894 和 2178 nm 的三个吸收带组成,分别分配给 7F6 → 5D4、7F6 → 7F0,1,2 和 7F6 → 7F3。光致发光(PL)和放射发光(RL)显示出相似的趋势,并且使用分光荧光计检查光学性质。纳米颗粒的尺寸经评估显示约为 8-16 nm,晶面距离为 2.1 Å。这项研究强调了 Tb3+ 和 Au 共掺杂材料在绿色光学应用中的潜力。
更新日期:2024-07-16
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