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Oxalamide ligands with additional coordinating groups for Cu-catalyzed arylation of alcohols and phenols
Chemical Communications ( IF 4.3 ) Pub Date : 2024-07-25 , DOI: 10.1039/d4cc02331e
Xiantong Yao , Xin Yang , Fanghua Chen , Rui Chen , Maolin Sun , Ruihua Cheng , Yueyue Ma , Jinxing Ye

A novel class of chain-like multidentate oxalamide ligands with additional coordinating groups was developed for the coupling of (hetero)aryl bromides with both alcohols and phenols under mild conditions. Introduction of oxygen atoms in N-alkyl chains is pivotal for the high catalytic efficiency and broad substrate versatility.

中文翻译:


具有额外配位基团的草酰胺配体用于铜催化醇和酚的芳基化



开发了一类具有额外配位基团的新型链状多齿草酰胺配体,用于在温和条件下将(杂)芳基溴与醇和酚偶联。在 N-烷基链中引入氧原子对于高催化效率和广泛的底物多功能性至关重要。
更新日期:2024-07-26
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