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Phosphorus-mediated hydrogenation catalysis
Nature Chemistry ( IF 19.2 ) Pub Date : 2024-07-24 , DOI: 10.1038/s41557-024-01588-9 Josh Abbenseth 1
Nature Chemistry ( IF 19.2 ) Pub Date : 2024-07-24 , DOI: 10.1038/s41557-024-01588-9 Josh Abbenseth 1
Affiliation
Hydrogenation catalysis is commonly associated with (noble) transition metals that undergo oxidative addition of H2 and subsequently transfer hydrogen atoms to unsaturated substrates. Now, a geometrically constrained phosphenium cation can facilitate both of these challenging transformations.
中文翻译:
磷介导的加氢催化
加氢催化通常与(贵)过渡金属相关,过渡金属经历 H2 的氧化加成,随后将氢原子转移到不饱和底物上。现在,几何约束的鏻阳离子可以促进这两个具有挑战性的转变。
更新日期:2024-07-24
中文翻译:
磷介导的加氢催化
加氢催化通常与(贵)过渡金属相关,过渡金属经历 H2 的氧化加成,随后将氢原子转移到不饱和底物上。现在,几何约束的鏻阳离子可以促进这两个具有挑战性的转变。