当前位置：
X-MOL 学术
›
Inorg. Chem.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Thorium Cluster Synthesized by a Solvent-Free Flux Approach: The Richest Coordination Diversity and Application Exploration
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2024-07-24 , DOI: 10.1021/acs.inorgchem.4c01373 Dan Zhou 1 , Yang Yang 1 , Zhehui Weng 2 , Jueqiong Wang 1 , Yizhou Yan 3 , Liwei Cheng 1 , Yingtong Fan 1 , Lixi Chen 1 , Hailong Zhang 1 , Long Chen 1 , Yanlong Wang 1 , Shuao Wang 1
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2024-07-24 , DOI: 10.1021/acs.inorgchem.4c01373 Dan Zhou 1 , Yang Yang 1 , Zhehui Weng 2 , Jueqiong Wang 1 , Yizhou Yan 3 , Liwei Cheng 1 , Yingtong Fan 1 , Lixi Chen 1 , Hailong Zhang 1 , Long Chen 1 , Yanlong Wang 1 , Shuao Wang 1
Affiliation
|
The renaissance of research interests in actinide oxo clusters in the past decade arises from both the concerns of radioactive contamination and their potential utility as nanoscale materials. Compared to the uranium cluster, the thorium (Th) cluster shows less coordination variation. Herein, we presented a unique Th cluster (ThC-1) that exhibits the most diverse coordination chemistry found within a single Th cluster via a solvent-free flux synthesis approach. The melt triazole not only offers a unique solvation environment that may be responsible for the coordination diversity in ThC-1 but also represents the first nitrogen-donor capping ligand in Th clusters. The potential utility of ThC-1 as a heterogeneous catalyst was also explored for a classical CO2 cycloaddition reaction. This work offers a novel approach in synthesizing Th clusters, broadening the realm of the structural diversity of Th.
中文翻译：
无溶剂助熔剂法合成钍团簇：最丰富的配位多样性及应用探索
过去十年，锕系氧簇研究兴趣的复兴源于对放射性污染的担忧及其作为纳米级材料的潜在用途。与铀团簇相比，钍（Th）团簇显示出较小的配位变化。在此，我们提出了一种独特的 Th 簇 ( ThC-1 )，它通过无溶剂助熔剂合成方法表现出在单个 Th 簇内发现的最多样化的配位化学。熔融三唑不仅提供了可能导致ThC-1配位多样性的独特溶剂化环境，而且代表了 Th 簇中的第一个氮供体封端配体。还探索了ThC-1作为多相催化剂在经典 CO 2环加成反应中的潜在用途。这项工作提供了一种合成 Th 簇的新方法，拓宽了 Th 结构多样性的领域。
更新日期：2024-07-24
中文翻译：
无溶剂助熔剂法合成钍团簇：最丰富的配位多样性及应用探索
过去十年，锕系氧簇研究兴趣的复兴源于对放射性污染的担忧及其作为纳米级材料的潜在用途。与铀团簇相比，钍（Th）团簇显示出较小的配位变化。在此，我们提出了一种独特的 Th 簇 ( ThC-1 )，它通过无溶剂助熔剂合成方法表现出在单个 Th 簇内发现的最多样化的配位化学。熔融三唑不仅提供了可能导致ThC-1配位多样性的独特溶剂化环境，而且代表了 Th 簇中的第一个氮供体封端配体。还探索了ThC-1作为多相催化剂在经典 CO 2环加成反应中的潜在用途。这项工作提供了一种合成 Th 簇的新方法，拓宽了 Th 结构多样性的领域。
京公网安备 11010802027423号