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Visible‐Light‐Induced Multi‐Component Nitrooxylation Reactions of α‐Diazoesters, Cyclic Ethers, and tert‐Butyl nitrite Leading to Organic Nitrate Esters
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2024-07-24 , DOI: 10.1002/chem.202402304
Cunwei Qian 1 , Xian Li 2 , Meng-Qing Gu 3
Affiliation  

A simple and efficient strategy has been developed for the synthesis of organic nitrate esters via visible‐light‐induced multi‐component nitrooxylation reactions of α‐diazoesters, cyclic ethers, and tert‐butyl nitrite under open air atmosphere. This transformation could be conducted under mild and metal‐free conditions to provide a number of organic nitrate esters in moderate to good yields using air as the green oxidant.

中文翻译:


可见光诱导 α-重氮酯、环醚和亚硝酸叔丁酯的多组分硝氧基化反应生成有机硝酸酯



我们开发了一种简单有效的策略,用于在露天气氛下通过可见光诱导的α-重氮酯、环醚和亚硝酸叔丁酯的多组分硝氧基化反应合成有机硝酸酯。这种转化可以在温和且无金属的条件下进行,使用空气作为绿色氧化剂,以中等至良好的产率提供多种有机硝酸酯。
更新日期:2024-07-24
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