Advanced 1D heterostructures based on nanotube templates and molecules,Chemical Society Reviews

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Advanced 1D heterostructures based on nanotube templates and molecules
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2024-07-22 , DOI: 10.1039/d3cs00467h
Charlotte Allard ₁ , Laurent Alvarez ₂ , Jean-Louis Bantignies ₂ , Nedjma Bendiab ₃ , Sofie Cambré ₄ , Stephane Campidelli ₅ , Jeffrey A Fagan ₆ , Emmanuel Flahaut ₇ , Benjamin Flavel ₈ , Frédéric Fossard ₉ , Etienne Gaufrès ₁₀ , Sebastian Heeg ₁₁ , Jean-Sebastien Lauret ₁₂ , Annick Loiseau ₉ , Jean-Baptiste Marceau ₁₀ , Richard Martel ₁₃ , Laëtitia Marty ₃ , Thomas Pichler ₁₄ , Christophe Voisin ₁₅ , Stephanie Reich ₁₆ , Antonio Setaro _{16,

17} , Lei Shi ₁₈ , Wim Wenseleers ₄

Affiliation

Ecole Polytechnique, Montreal, Canada.
Laboratoire Charles Coulomb, CNRS-Université de Montpellier, France.
CNRS-Université de Grenoble, France.
University of Antwerp, Belgium.
CEA-Saclay, France.
National Institute of Standards and Technology (NIST), USA.
CIRIMAT, Université Toulouse 3 Paul Sabatier, Toulouse INP, CNRS, Université de Toulouse, 118 Route de Narbonne, 31062 Toulouse, cedex 9, France.
Karlsruhe Institute of Technology (KIT), Germany.
Laboratoire d'Étude des Microstructures, CNRS-Onera, Chatillon, France.
Laboratoire Photonique, Numérique et Nanosciences, CNRS-Université de Bordeaux-IOGS, Talence, France.
Humboldt-Universität zu Berlin, Germany.
LUMIN, Université Paris Saclay, ENS Paris Saclay, Centrale Supelec, CNRS, Orsay, France.
University of Montreal, Canada.
University of Vienna, Austria.
Université de Paris, Ecole Normale Paris, CNRS, PSL, France.
Free University of Berlin, Germany.
Faculty of Engineering and Informatics, Pegaso University, Naples, Italy.
State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, Nanotechnology and Research Center, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510275, China.

Recent advancements in materials science have shed light on the potential of exploring hierarchical assemblies of molecules on surfaces, driven by both fundamental and applicative challenges. This field encompasses diverse areas including molecular storage, drug delivery, catalysis, and nanoscale chemical reactions. In this context, the utilization of nanotube templates (NTs) has emerged as promising platforms for achieving advanced one-dimensional (1D) molecular assemblies. NTs offer cylindrical, crystalline structures with high aspect ratios, capable of hosting molecules both externally and internally (Mol@NT). Furthermore, NTs possess a wide array of available diameters, providing tunability for tailored assembly. This review underscores recent breakthroughs in the field of Mol@NT. The first part focuses on the diverse panorama of structural properties in Mol@NT synthesized in the last decade. The advances in understanding encapsulation, adsorption, and ordering mechanisms are detailed. In a second part, the review highlights the physical interactions and photophysics properties of Mol@NT obtained by the confinement of molecules and nanotubes in the van der Waals distance regime. The last part of the review describes potential applicative fields of these 1D heterostructures, providing specific examples in photovoltaics, luminescent materials, and bio-imaging. A conclusion gathers current challenges and perspectives of the field to foster discussion in related communities.

中文翻译：

基于纳米管模板和分子的先进一维异质结构

材料科学的最新进展揭示了在基本和应用挑战的推动下探索表面分子分层组装的潜力。该领域涵盖分子存储、药物输送、催化和纳米级化学反应等多个领域。在这种背景下，纳米管模板（NT）的利用已成为实现先进一维（1D）分子组装的有前途的平台。 NT 提供具有高纵横比的圆柱形晶体结构，能够在外部和内部容纳分子 (Mol@NT)。此外，NT 拥有多种可用直径，为定制组装提供可调性。这篇综述强调了 Mol@NT 领域最近的突破。第一部分重点介绍过去十年合成的 Mol@NT 的各种结构特性。详细介绍了在理解封装、吸附和排序机制方面的进展。在第二部分中，综述重点介绍了通过将分子和纳米管限制在范德华距离范围内而获得的 Mol@NT 的物理相互作用和光物理特性。综述的最后部分描述了这些一维异质结构的潜在应用领域，提供了光伏、发光材料和生物成像方面的具体例子。结论收集了该领域当前的挑战和观点，以促进相关社区的讨论。

更新日期：2024-07-22

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