Lewis acid‐base interactions are common in chemical processes presented in diverse applications, such as synthesis, catalysis, batteries, semiconductors, and solar cells. The Lewis acid‐base interactions allow precise tuning of material properties from the molecular level to more aggregated and organized structures. This review will focus on the origin, development, and prospects of applying Lewis acid‐base interactions for the materials design and mechanism understanding in the advancement of battery materials and chemistries. The covered topics relate to aqueous batteries, lithium‐ion batteries, solid‐state batteries, alkali metal‐sulfur batteries, and alkali metal‐oxygen batteries. In this review, the Lewis acid‐base theories will be first introduced. Thereafter the application strategies for Lewis acid‐base interactions in solid‐state and liquid‐based batteries will be introduced from the aspects of liquid electrolyte, solid polymer electrolyte, metal anodes, and high‐capacity cathodes. The underlying mechanism is highlighted in regard to ion transport, electrochemical stability, mechanical property, reaction kinetics, dendrite growth, corrosion, and so on. Last but not least, perspectives on the future directions related to Lewis acid‐base interactions for next‐generation batteries are like to be shared.

中文翻译：

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新兴电池中路易斯酸碱相互作用的展望


路易斯酸碱相互作用在合成、催化、电池、半导体和太阳能电池等多种应用中的化学过程中很常见。路易斯酸碱相互作用允许从分子水平到更聚集和有组织的结构精确调节材料特性。本综述将重点介绍路易斯酸碱相互作用在电池材料和化学进展中应用材料设计和机制理解的起源、发展和前景。涵盖的主题涉及水系电池、锂离子电池、固态电池、碱金属硫电池和碱金属氧电池。在这篇综述中，将首先介绍路易斯酸碱理论。随后将从液体电解质、固体聚合物电解质、金属负极和高容量正极等方面介绍路易斯酸碱相互作用在固态和液基电池中的应用策略。重点介绍了离子传输、电化学稳定性、机械性能、反应动力学、枝晶生长、腐蚀等方面的潜在机制。最后但并非最不重要的一点是，人们希望分享与下一代电池的路易斯酸碱相互作用相关的未来方向的观点。