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Leveraging intramolecular electrostatics to boost electrocatalytic CO2 reduction
Chem Catalysis ( IF 11.5 ) Pub Date : 2024-07-18 , DOI: 10.1016/j.checat.2024.101053 David S. Tresp , Demyan E. Prokopchuk
中文翻译:
利用分子内静电促进电催化二氧化碳还原
更新日期:2024-07-19
Chem Catalysis ( IF 11.5 ) Pub Date : 2024-07-18 , DOI: 10.1016/j.checat.2024.101053 David S. Tresp , Demyan E. Prokopchuk
In a recent issue of Chem Catalysis, McCrory et al. present bimetallic CO2 reduction reaction (CO2RR) electrocatalysts. They demonstrate that a heterometallic molecular Co-Zn catalyst, with each metal nestled into a separate pyridyldiimine ligand pocket, operates faster and more efficiently than the Co-Co analogue, emphasizing the importance of electrostatics in multimetallic electrocatalysts.
中文翻译:
利用分子内静电促进电催化二氧化碳还原
在最近一期的《化学催化》中,McCrory 等人。提出了双金属CO 2 还原反应(CO 2 RR)电催化剂。他们证明,每种金属都位于单独的吡啶二亚胺配体口袋中的异金属分子 Co-Zn 催化剂比 Co-Co 类似物运行更快、更有效,这强调了静电在多金属电催化剂中的重要性。