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Unlocking the potential of a MOF-derived CaMoO4 electrode for high performance supercapacitor application
New Journal of Chemistry ( IF 2.7 ) Pub Date : 2024-07-18 , DOI: 10.1039/d4nj02563f
Palanisamy Rajkumar 1 , Joel Kingston Ramesh 2 , Vediyappan Thirumal 1 , Maalavika S. Iyer 3 , R. Margrate Bhackiyavathi Princess 4 , R. M. Gnanamuthu 5 , Kisoo Yoo 1 , Jinho Kim 1
Affiliation  

This manuscript presents a novel method to enhance the electrochemical performance of CaMoO4 for supercapacitors by synthesizing it from a bi-metallic metal–organic framework (MOF). The resulting CaMoO4 nanoparticles retain MOF characteristics, with a high surface area, and demonstrate improved performance over conventionally synthesized CaMoO4. Electrochemical tests showed the MOF-derived CaMoO4 achieved a high capacitance of 377.82 F g−1 at 1 A g−1 and retained 91% of its capacitance after 5000 cycles. The assembled asymmetric supercapacitor also retained 88% of its capacitance after 10 000 cycles, highlighting the potential of this approach for enhancing energy storage devices.

中文翻译:


释放 MOF 衍生的 CaMoO4 电极在高性能超级电容器应用中的潜力



该手稿提出了一种通过从双金属金属有机框架(MOF)合成CaMoO 4 来增强超级电容器电化学性能的新方法。所得的 CaMoO 4 纳米粒子保留了 MOF 的特性,具有高表面积,并且比传统合成的 CaMoO 4 表现出更好的性能。电化学测试表明,MOF 衍生的 CaMoO 4 在 1 A g −1 下实现了 377.82 F g −1 的高电容,并在 5000 次后保留了 91% 的电容循环。组装的非对称超级电容器在 10000 次循环后还保留了 88% 的电容,凸显了这种方法在增强储能设备方面的潜力。
更新日期:2024-07-19
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