For the construction of Csp³–Csp³ bonds, cross-coupling reactions in Ni/photoredox dual catalysis have recently achieved significant progress compared to traditional ones. In the past five years, a variety of free radical precursors have been developed to participate in redox neutral and reductive cross-coupling reactions via a dual photoredox/Ni-catalytic process. In this minireview, we mainly focus on the recent advancements (from 2019 to 2023) in Ni/photoredox dual catalysis for Csp³–Csp³ cross-coupling reactions.

中文翻译：

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Ni/光氧化还原双催化Csp3-Csp3交叉偶联反应的最新进展


对于Csp ³ –Csp ³ 键的构建，Ni/光氧化还原双催化中的交叉偶联反应与传统反应相比最近取得了显着进展。在过去的五年中，人们开发了多种自由基前体，通过光氧化还原/镍双催化过程参与氧化还原中性和还原性交叉偶联反应。在这篇小综述中，我们主要关注 Ni/光氧化还原双催化 Csp ³ –Csp ³ 交叉偶联反应的最新进展（从 2019 年到 2023 年）。