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Pd(II)-Catalyzed Formal [5+2]-Carbocyclization of Ortho-Aryl-Substituted Arylaldehydes with Allylic Alcohols
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2024-07-03 , DOI: 10.1002/adsc.202400568 Wei Zeng 1 , Huanfeng Jiang 1 , Chengjie Wang 1
中文翻译：
Pd(II) 催化邻芳基取代的芳醛与烯丙醇的缩甲醛 [5+2]-碳环化
更新日期：2024-07-03
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2024-07-03 , DOI: 10.1002/adsc.202400568 Wei Zeng 1 , Huanfeng Jiang 1 , Chengjie Wang 1
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A Pd(II)-catalyzed formal [5+2] coupling-cyclization of 2-arylbenzaldehydes with allylic alcohols has been developed. The method provides an efficient approach to access diaryl-fused cycloheptene skeletons via traceless α-amino acid-assisted Csp2−H activation process.
中文翻译：
Pd(II) 催化邻芳基取代的芳醛与烯丙醇的缩甲醛 [5+2]-碳环化
开发了 Pd(II) 催化的 2-芳基苯甲醛与烯丙醇的正式 [5+2] 偶联环化反应。该方法提供了一种通过无痕α-氨基酸辅助的C sp 2 -H 活化过程获取二芳基稠合环庚烯骨架的有效方法。
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