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Construction of a redox-active metal−organic framework with an octanuclear lithium one-dimensional building block
Chemical Communications ( IF 4.3 ) Pub Date : 2024-07-03 , DOI: 10.1039/d4cc02111h
Shufan Li, Ya-Ru Meng, Min-Jie Xu, Gen Zhang, Jian Su

A stable lithium metal-organic framework, constructed using a redox-active N,N,N',N'-tetrakis(4-carboxyphenyl)-1,4-phenylenediamine linker and Li8 cluster-based one-dimensional rod secondary building unit, exhibits good stability and reversible redox activity. The Li8-MOF, which can be oxidized by AgNO3, has the potential to function as an electrochromic device, thereby advancing the development of smart MOF materials.

中文翻译:


用八核锂一维结构单元构建氧化还原活性金属有机框架



稳定的锂金属有机框架,采用氧化还原活性 N,N,N',N'-四(4-羧基苯基)-1,4-苯二胺连接体和基于 Li8 簇的一维棒二级结构单元构建,具有良好的稳定性和可逆的氧化还原活性。 Li8-MOF可被AgNO3氧化,具有作为电致变色器件的潜力,从而推动智能MOF材料的发展。
更新日期:2024-07-03
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