Synthesis of N-triflyl aldimines catalyzed by imino-λ3-iodane,Organic Chemistry Frontiers

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Synthesis of N-triflyl aldimines catalyzed by imino-λ3-iodane
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2024-07-01 , DOI: 10.1039/d4qo00875h
Shun Sunagawa ₁ , Yoko Tezuka ₁ , Akira Tsubouchi ₁ , Akira Yoshimura ₂ , Akio Saito ₁

Affiliation

We report a catalytic synthesis of N-triflyl aldimines from aldehydes and triflylamide using imino-λ³-iodane generated in situ from an iodosylarene precatalyst and triflylamide. In the present reaction, imino-λ³-iodane works as an acid–base cooperative catalyst to activate aldehydes and triflylamide.

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