In recent years, redox reactions have harnessed light or mechanical energy to enable the formation of chemical bonds. We postulated a complementary approach that electromagnetic induction could promote the redox reaction of organic molecules using a rotating magnetic field and metal rods. Here, we report that electromotive force activates the redox-active trifluoromethylating reagents. This magnetoredox system can be applied to the trifluoromethylation of heteroarenes with high regioselectivity and hydrotrifluoromethylation of alkenes without the need for catalysts and organic additives.

中文翻译：

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使用旋转磁场和金属棒的有机分子的氧化还原反应


近年来，氧化还原反应利用光或机械能来形成化学键。我们假设了一种补充方法，即电磁感应可以使用旋转磁场和金属棒促进有机分子的氧化还原反应。在这里，我们报告电动势激活氧化还原活性三氟甲基化试剂。该磁氧化还原体系可应用于杂芳烃的高区域选择性三氟甲基化和烯烃的氢三氟甲基化，无需催化剂和有机添加剂。