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Constructing molecularly imprinted membranes with instant noodles-like structure for selectively separating acteoside
Analytica Chimica Acta ( IF 5.7 ) Pub Date : 2024-06-26 , DOI: 10.1016/j.aca.2024.342915
Chen Chen , Qiong Zhang , Yun Cheng , Yingying Fan , Mujin Fang , Kui Li , Xueqin Li

Acteoside (ACT) was the main bioactive components in phenylethanoid glycosides of . Currently, the development of an efficient method for selectively separating ACT was crucial. Consequently, yolk-shell magnetic mesoporous carbon (YSMMC) was synthesized as a nanofiller to prepare molecularly imprinted membranes (ACT-MIMs) with instant noodles-like structure for selectively separating ACT. The numerous YSMMC were moved to the upper surface of ACT-MIMs by magnetic guidance and constructed the instant noodles-like structure in ACT-MIMs. The instant noodle-like structure increased the surface roughness of ACT-MIMs, which was conducive to improving the effective imprinted interface, increasing the selectivity of ACT-MIMs. In addition, the instant noodle-like structure had dendritic interleaved pathways in ACT-MIMs. The dendritic interleaved pathways can intercept ACT through ACT-MIMs, enhancing the permselectivity of ACT-MIMs. The prepared YSMMC possessed the dendritic shell and interlayer cavity structure can provide a great accommodation space, improving the rebinding capacities of ACT-MIMs. The high permselectivity (14.49), remarkable selectivity (7.52), and excellent rebinding capacity (120.48 mg/g) were achieved for the prepared ACT-MIMs. Thus, the design of ACT-MIMs with the instant noodles-like structure were valuable for selectively separating of bioactive components.

中文翻译:


构建类方便面结构分子印迹膜选择性分离类叶升麻苷



Acteoside (ACT) 是苯乙醇苷类中的主要生物活性成分。目前,开发一种有效的选择性分离 ACT 的方法至关重要。因此,合成了蛋黄壳磁性介孔碳(YSMMC)作为纳米填料,制备了具有方便面状结构的分子印迹膜(ACT-MIM),用于选择性分离ACT。众多的YSMMC通过磁力引导移动到ACT-MIM的上表面,并在ACT-MIM中构建方便面状的结构。方便面状结构增加了ACT-MIMs的表面粗糙度,有利于改善有效压印界面,提高ACT-MIMs的选择性。此外,方便面状结构在 ACT-MIM 中具有树突状交错通路。树突状交错通路可以通过 ACT-MIM 拦截 ACT,从而增强 ACT-MIM 的通透选择性。制备的YSMMC具有树枝状壳和层间空腔结构,可以提供很大的容纳空间,提高ACT-MIM的重结合能力。所制备的 ACT-MIM 具有高选择性渗透性 (14.49)、显着的选择性 (7.52) 和出色的再结合能力 (120.48 mg/g)。因此,设计具有类似方便面结构的ACT-MIM对于选择性分离生物活性成分具有重要意义。
更新日期:2024-06-26
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