A nickel‐catalyzed reductive amidation of aryl sulfonium salts with isocyanates for amide synthesis via C‐S bond cleavage was developed. The reactions proceeded smoothly at ambient temperature in the presence of nickel catalyst and manganese metal in DMF to give a variety of amides in moderate to good yields with wide functional group tolerance.

中文翻译：

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镍催化芳基锍盐与异氰酸酯的还原酰胺化反应，通过 C-S 键活化合成酰胺


开发了一种镍催化的芳基锍盐与异氰酸酯的还原酰胺化反应，通过 C-S 键断裂合成酰胺。在镍催化剂和锰金属存在下，反应在 DMF 中于环境温度下顺利进行，以中等至良好的收率生成各种具有广泛官能团耐受性的酰胺。