2D materials (2DMs), known for their atomically ultrathin structure, exhibit remarkable electrical and optical properties. Similarly, molecular self‐assembled monolayers (SAMs) with comparable atomic thickness show an abundance of designable structures and properties. The strategy of constructing electronic devices through unique heterostructures formed by van der Waals assembly between 2DMs and molecular SAMs not only enables device miniaturization, but also allows for convenient adjustment of their structures and functions. In this review, the fundamental structures and fabrication methods of three different types of electronic devices dominated by 2DM‐SAM heterojunctions with varying architectures are timely elaborated. Based on these heterojunctions, their fundamental functionalities and characteristics, as well as the regulation of their performance by external stimuli, are further discussed.

中文翻译：

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基于二维材料异质结构和自组装单分子层的电子器件


二维材料 (2DM) 以其原子级超薄结构而闻名，表现出卓越的电学和光学特性。同样，具有可比原子厚度的分子自组装单层（SAM）显示出丰富的可设计结构和特性。通过2DM和分子SAM之间的范德华组装形成的独特异质结构来构建电子器件的策略不仅使器件小型化，而且还可以方便地调整其结构和功能。在这篇综述中，及时阐述了以不同架构的 2DM-SAM 异质结为主的三种不同类型电子器件的基本结构和制造方法。基于这些异质结，进一步讨论了它们的基本功能和特性，以及外部刺激对其性能的调节。