Front Cover: An Atypically Bent Isocyanide at Iron in a Tetrapodal Penta-Carbene Framework (Eur. J. Inorg. Chem. 18/2024),European Journal of Inorganic Chemistry

当前位置： X-MOL 学术 › Eur. J. Inorg. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Front Cover: An Atypically Bent Isocyanide at Iron in a Tetrapodal Penta-Carbene Framework (Eur. J. Inorg. Chem. 18/2024)
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2024-06-25 , DOI: 10.1002/ejic.202481801
Michael R. Gau ₁ , Taylor M. Keller ₁ , Jeremiah J. Scepaniak ₂

Affiliation

The Front Cover shows a complex of iron supported in a tetrapodal penta-carbene framework exhibiting an unexpected and rare nonlinear tertbutylisocyanide moiety symbolized by a bent spoon amongst an otherwise normal table setting. The short Fe−C bond of 1.8076(18) Å, an Fe−C−N bond angle of 169.63(16)° and a bond angle of 142.67(18)° about the isocyanide nitrogen atom are consistent with sp and sp² hybridization, respectively. These metrics are consistent with the carbenic resonance form of isocyanide bonding that is induced by excellent π-backbonding and rarely observed at iron; thereby exemplifying the excellent donor ability of our penta-carbene ligand. More information can be found in the Research Article by J. J. Scepaniak and co-workers.

中文翻译：

封面：四足五碳烯框架中铁的非典型弯曲异氰化物（Eur. J. Inorg. Chem. 18/2024）

封面展示了由四足五碳烯框架支撑的铁复合物，呈现出意想不到且罕见的非线性叔丁基异氰化物部分，在正常的餐桌布置中以弯曲的勺子为象征。短Fe−C键为1.8076(18) Å，Fe−C−N键角为169.63(16)°，异氰氮原子的键角为142.67(18)°，与sp和sp 分别杂交。这些指标与异氰化物键合的碳共振形式一致，异氰化物键合是由优异的 π-背键合诱导的，并且在铁上很少观察到；从而证明了我们的五卡宾配体优异的供体能力。更多信息可以在 J. J. Scepaniak 及其同事的研究文章中找到。

更新日期：2024-06-30

点击分享查看原文

点击收藏

公开下载

阅读更多本刊新发论文本刊介绍/投稿指南