npj Clean Water ( IF 10.4 ) Pub Date : 2024-06-18 , DOI: 10.1038/s41545-024-00347-0 Menghan Hu , Na Xie , Yujia Huang , Yikai Yu
It was observed that a super-efficient gel adsorbent system (RRQG@CDC) could be obtained when a matrix material of polyquaternium gel with a flat distribution (RRQG) was loaded onto a skeleton material of cyclodextrin carbide (CDC). The results showed that the adsorption capacity of RRQG@CDC towards dyes was 1250 times higher than that of commonly used activated carbon, enabling highly efficient purification of dyeing wastewater through superior adsorption. In addition, RRQG@CDC demonstrated adaptability to a range of different pH values and salinity conditions, showing super-efficient adsorption abilities towards various types of dyes. Moreover, simulated scale-up tests confirmed the feasibility of this super-efficient adsorbent for practical engineering applications. An enhanced quasi-planar electrostatic adsorption mechanism model was established, which has changed the traditional understanding of adsorption mechanisms. Furthermore, the waste residues of RRQG@CDC, after dye adsorption, can be directly utilized as high-calorific fuels, showcasing the resourcefulness of these residues while eliminating the risk of secondary pollution. In conclusion, this study achieved a remarkably efficient and resource-based purification of dyeing wastewater by developing a highly effective adsorbent system.
中文翻译:
超高效凝胶吸附剂,吸附能力是活性炭1000倍以上
结果表明,当将具有平坦分布的聚季铵盐凝胶基质材料(RRQG)负载到碳化环糊精(CDC)骨架材料上时,可以获得超高效凝胶吸附系统(RRQG@CDC)。结果表明,RRQG@CDC对染料的吸附能力比常用活性炭高1250倍,能够通过卓越的吸附作用高效净化印染废水。此外,RRQG@CDC表现出对一系列不同pH值和盐度条件的适应性,对各种类型的染料表现出超高效的吸附能力。此外,模拟放大试验证实了这种超高效吸附剂在实际工程应用中的可行性。建立了增强的准平面静电吸附机理模型,改变了对吸附机理的传统认识。此外,RRQG@CDC的废渣经过染料吸附后,可以直接作为高热值燃料利用,展现了这些废渣的智慧,同时消除了二次污染的风险。总之,本研究通过开发高效的吸附剂系统,实现了印染废水的高效、资源化净化。