Two-dimensional heterostructures (2D HSs) are popular candidates for sustainable energy conversion and storage applications through the synergetic combination of nanosized heterojunctions with intriguing functionalities. The properties of 2D heterointerfaces can be well-regulated for scaled-up applications through synthetic tuning and/or engineering design. In this perspective, the synthesis protocols of 2D heterostructure are first discussed, along with associated modulation strategies to better describe the required functionalities for scaled-up applications. Computational insights are also provided to regulate and predict the heterointerface of the outlined structures based on various models (e.g., atomic, micro, and mesoscale simulations). The role of modulated 2D heterostructures is highlighted with respect to the energy applications along with the current challenges for 2D heterostructure development. This review is anticipated to deliver new paths for the design and construction of 2D heterostructures toward the practical applications in multiple fields with a focus on energy conversion and storage.

中文翻译：

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用于能量转换和存储应用的二维层状异质结构的合成和调制的先进策略


通过纳米异质结与有趣功能的协同组合，二维异质结构（2D HS）成为可持续能源转换和存储应用的热门候选材料。通过综合调谐和/或工程设计，可以很好地调节二维异质界面的特性，以适应放大的应用。从这个角度来看，首先讨论了二维异质结构的合成协议，以及相关的调制策略，以更好地描述放大应用所需的功能。还提供计算见解，以根据各种模型（例如原子、微观和介观模拟）调节和预测概述结构的异质界面。调制二维异质结构在能源应用方面的作用以及当前二维异质结构开发的挑战得到了强调。此次审查预计将为二维异质结构的设计和构建提供新的途径，以实现多个领域的实际应用，重点是能量转换和存储。