The pursuit of achieving both ceramic-like hardness and polymer-like flexibility in a coating, known as a polymer–ceramic hybrid coating, is a challenging yet highly desirable goal. The application of these coatings spans various domains such as foldable displays, wearable devices, maritime industries, and biomedical engineering. Particularly, endowing polymer–ceramic hybrid coatings with functions such as transparency, anti-liquid adhesion, anti-biofouling, and self-healing expand their potential in fields necessitating highly protective performance, which have gained significant attention in recent years. In this comprehensive review, our main objective is to provide interested readers with a clear framework for assessment and future exploration of this topic. We systematically outline the fundamentals of functional polymer-ceramic hybrid coatings, explaining their fabrication intricacies. Additionally, we explore their practical applications, intricately tailored to the unique requirements of each field. Concluding our review, we address the key challenges facing modern functional polymer–ceramic coatings and propose potential paths for future advancements.

中文翻译：

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功能性聚合物-陶瓷杂化涂层：现状、进展和趋势


追求在涂层（称为聚合物陶瓷混合涂层）中同时实现陶瓷般的硬度和聚合物般的柔韧性是一个具有挑战性但非常理想的目标。这些涂层的应用涵盖可折叠显示器、可穿戴设备、海事工业和生物医学工程等各个领域。特别是赋予聚合物陶瓷杂化涂层透明、抗液体粘附、抗生物污损和自修复等功能，扩大了其在需要高防护性能的领域的潜力，近年来受到了极大的关注。在这篇全面的评论中，我们的主要目标是为感兴趣的读者提供一个清晰的框架来评估和未来探索该主题。我们系统地概述了功能性聚合物陶瓷混合涂层的基本原理，解释了它们的制造复杂性。此外，我们还探索它们的实际应用，根据每个领域的独特要求进行精心定制。在总结我们的审查时，我们解决了现代功能聚合物陶瓷涂层面临的主要挑战，并提出了未来发展的潜在路径。