Highly Active Oxidation Catalysts through Confining Pd Clusters on CeO2 Nano-Islands,Angewandte Chemie International Edition

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Highly Active Oxidation Catalysts through Confining Pd Clusters on CeO2 Nano-Islands
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-06-15 , DOI: 10.1002/anie.202408511
Daria Gashnikova ₁ , Florian Maurer ₁ , Eric Sauter ₂ , Sarah Bernart ₃ , Jelena Jelic ₃ , Paolo Dolcet _{1,

4} , Carina B Maliakkal ₅ , Yuemin Wang ₂ , Christof Wöll ₂ , Felix Studt ₃ , Christian Kübel _{5,

6} , Maria Casapu ₁ , Jan-Dierk Grunwaldt _{1,

3}

Affiliation

Synthesis approach towards rational tailoring the threshold of cluster formation in noble metal-ceria catalysts using CeO₂ islands finely distributed on Al₂O₃ support. The spatial separation of CeO₂ entities prevents highly active Pd clusters from redispersion and strong sintering during CO oxidation reaction.

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