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4,9-Dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b′]dithiophene as a π-Spacer of Donor−π–Acceptor Dye and Its Photovoltaic Performance with Liquid and Solid-State Dye-Sensitized Solar Cells
Organic Letters ( IF 4.9 ) Pub Date : 2013-12-11 00:00:00 , DOI: 10.1021/ol402749s
Liping Cai 1 , Thomas Moehl 2 , Soo-Jin Moon 2 , Jean-David Decoppet 2 , Robin Humphry-Baker 2 , Zhaosheng Xue 1 , Liu Bin 1 , Shaik M Zakeeruddin 2 , Michael Grätzel 2
Affiliation  

A new D−π-A organic dye, LC-5, containing 4,9-dihydro-4,4,9,9-tetrahexyl-s-indaceno[1,2-b:5,6-b′]-dithiophene as a novel π-conjugated spacer has been synthesized and tested as a sensitizer in dye-sensitized solar cells (DSC). Volatile and ionic liquid electrolytes have been used in conjunction with the synthesized dye, and the electrolyte influence on the photovoltaic performance of DSCs was investigated. A detailed investigation, including transient photocurrent/photovoltage decay measurements and electrochemical impedance spectroscopy data, provide important conclusions about the influence of electrolytes on the photovoltaic parameters.

中文翻译:

4,9-二氢4,4,9,9-tetrahexyl-小号-indaceno [1,2 b:5,6- b ']二噻吩作为供体-π-受体染料及其光伏性能的π-间隔液态和固态染料敏化太阳能电池

一种新的d-π-A有机染料,含LC-5,4,9-二氢- 4,4,9,9-tetrahexyl-小号-indaceno [1,2 b:5,6- b ']二噻吩作为新型的π共轭间隔基,已经合成并作为染料敏化太阳能电池(DSC)中的敏化剂进行了测试。已将挥发性和离子液体电解质与合成染料结合使用,并研究了电解质对DSC光伏性能的影响。包括瞬态光电流/光电压衰减测量和电化学阻抗谱数据在内的详细研究提供了有关电解质对光伏参数影响的重要结论。
更新日期:2013-12-11
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