Redox-Neutral 1,2-Dicarbofunctionalization of Buta-1,3-diene by Merging Decatungstate and Chromium Catalysis,Synthesis

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Redox-Neutral 1,2-Dicarbofunctionalization of Buta-1,3-diene by Merging Decatungstate and Chromium Catalysis
Synthesis ( IF 2.2 ) Pub Date : 2024-06-03 , DOI: 10.1055/a-2328-3037
Du Ding ₁ , Pu-Sheng Wang ₂

Affiliation

Homoallylic alcohol is a significantly useful intermediate in organic synthesis. Here we establish a three-component Nozaki–Hiyama–Kishi (NHK) type reaction of buta-1,3-diene, aldehydes, and aliphatic C–H partners by merging decatungstate and chromium catalysis, enabling a modular, redox-neutral, and atom-economic strategy to access a diverse range of homoallylic alcohols.

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