5-Hydroxymethylfurfural and its Downstream Chemicals: A Review of Catalytic Routes,Advanced Materials

当前位置： X-MOL 学术 › Adv. Mater. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

5-Hydroxymethylfurfural and its Downstream Chemicals: A Review of Catalytic Routes
Advanced Materials ( IF 27.4 ) Pub Date : 2024-05-29 , DOI: 10.1002/adma.202311464
Chunlin Chen _{1,

2} , Mingxin Lv _{1,

2} , Hualei Hu _{1,

2} , Liyuan Huai _{1,

2} , Bin Zhu _{1,

2} , Shilin Fan _{1,

2} , Qiuge Wang _{1,

2} , Jian Zhang _{1,

2}

Affiliation

Biomass assumes an increasingly vital role in the realm of renewable energy and sustainable development due to its abundant availability, renewability, and minimal environmental impact. Within this context, 5-hydroxymethylfurfural (HMF), derived from sugar dehydration, stands out as a critical bio-derived product. It serves as a pivotal multifunctional platform compound, integral in synthesizing various vital chemicals, including furan-based polymers, fine chemicals, and biofuels. The high reactivity of HMF, attributed to its highly active aldehyde, hydroxyl, and furan ring, underscores the challenge of selectively regulating its conversion to obtain the desired products. This review highlights the research progress on efficient catalytic systems for HMF synthesis, oxidation, reduction, and etherification. Additionally, it outlines the techno-economic analysis (TEA) and prospective research directions for the production of furan-based chemicals. Despite significant progress in catalysis research, and certain process routes demonstrating substantial economics, with key indicators surpassing petroleum-based products, a gap persists between fundamental research and large-scale industrialization. This is due to the lack of comprehensive engineering research on bio-based chemicals, making the commercialization process a distant goal. These findings provide valuable insights for further development of this field.

中文翻译：

5-羟甲基糠醛及其下游化学品：催化路线综述

生物质因其丰富的可用性、可再生性和对环境的影响最小，在可再生能源和可持续发展领域发挥着越来越重要的作用。在此背景下，源自糖脱水的 5-羟甲基糠醛 (HMF) 成为一种重要的生物衍生产品。它是一种关键的多功能平台化合物，是合成各种重要化学品的重要组成部分，包括呋喃基聚合物、精细化学品和生物燃料。 HMF 的高反应活性归因于其高活性的醛、羟基和呋喃环，这凸显了选择性调节其转化以获得所需产物的挑战。本文重点介绍了HMF合成、氧化、还原和醚化高效催化系统的研究进展。此外，它还概述了呋喃类化学品生产的技术经济分析（TEA）和前瞻性研究方向。尽管催化研究取得了重大进展，某些工艺路线具有显着的经济性，关键指标超越石油产品，但基础研究与大规模产业化之间仍然存在差距。这是由于生物基化学品缺乏全面的工程研究，使得商业化进程成为一个遥远的目标。这些发现为该领域的进一步发展提供了宝贵的见解。

更新日期：2024-05-29

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南