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阴离子调节银咪唑立方八面体笼微环境以实现高效电催化二氧化碳还原
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-05-20 , DOI: 10.1002/anie.202406564 Wenqian Yang 1 , Qijie Mo 1 , Qi-Ting He 1 , Xiang-Ping Li 1 , Ziqian Xue 2 , Yu-Lin Lu 1 , Jie Chen 1 , Kai Zheng 1 , Yanan Fan 1 , Guangqin Li 1 , Cheng-Yong Su 1
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我们制备了三种Ag 4 L 4型立方八面体配位笼(Ag-MOC-X、X=NO 3 、ClO 4 、BF 4 ),它们表现出内/外配位微环境和金属/非金属活性位点,可协同增强选择性在pH通用电解质中将CO 2电催化还原为CO。
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