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Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2024-05-14 , DOI: 10.1021/acs.cgd.3c01537
Yaoguo Shen 1 , Yu Wang 1 , Zixiang Chen 1 , WenCheng Lu 1
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2024-05-14 , DOI: 10.1021/acs.cgd.3c01537
Yaoguo Shen 1 , Yu Wang 1 , Zixiang Chen 1 , WenCheng Lu 1
Affiliation
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The present study reports an organic–inorganic hybrid birefringent crystal material, Zn(C6H4NO2)2·4H2O, exhibiting a short cutoff edge (274 nm) in the solar-blind ultraviolet region. This material exhibits large optical anisotropy with a birefringence of 0.37@550 nm. Furthermore, we indentified the (C6H4NO2)− anionic group as a good birefringence-active gene for the first time and compared it comprehensively with other six-membered ring compounds to showcase its excellent optical performance. Moreover, our findings have further advanced the upper limit of birefringence for zinc-based six-membered ring compounds in the solar-blind ultraviolet region.
中文翻译:
Zn(C6H4NO2)2·4H2O:日盲双折射晶体
本研究报道了一种有机-无机杂化双折射晶体材料Zn(C 6 H 4 NO 2 ) 2 ·4H < b4> O,在日盲紫外区域表现出短截止边缘(274 nm)。该材料表现出较大的光学各向异性,双折射率为 0.37@550 nm。此外,我们将 (C 6 H 4 NO 2 ) − 阴离子基团鉴定为第一个良好的双折射活性基因。时间并将其与其他六元环化合物进行全面比较,展示其优异的光学性能。此外,我们的研究结果进一步提高了锌基六元环化合物在日盲紫外区双折射的上限。
更新日期:2024-05-14
中文翻译:

Zn(C6H4NO2)2·4H2O:日盲双折射晶体
本研究报道了一种有机-无机杂化双折射晶体材料Zn(C 6 H 4 NO 2 ) 2 ·4H < b4> O,在日盲紫外区域表现出短截止边缘(274 nm)。该材料表现出较大的光学各向异性,双折射率为 0.37@550 nm。此外,我们将 (C 6 H 4 NO 2 ) − 阴离子基团鉴定为第一个良好的双折射活性基因。时间并将其与其他六元环化合物进行全面比较,展示其优异的光学性能。此外,我们的研究结果进一步提高了锌基六元环化合物在日盲紫外区双折射的上限。