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Electrohydrodynamic Inkjet Printing of Three-Dimensional Perovskite Nanocrystal Arrays for Full-Color Micro-LED Displays
ACS Applied Materials & Interfaces ( IF 8.3 ) Pub Date : 2024-05-05 , DOI: 10.1021/acsami.4c02594 Yihang Chen 1, 2 , Xiao Yang 1, 2, 3 , Xiaotong Fan 1, 2 , Ao Kang 1, 2 , Xuemin Kong 1, 2 , Guolong Chen 1, 2 , Chenming Zhong 1, 2 , Yijun Lu 1, 2, 4 , Yi Fan 2, 5 , Xu Hou 2, 4, 5 , Tingzhu Wu 1, 2, 4 , Zhong Chen 1, 2, 3, 4 , Shuli Wang 1, 2 , Yue Lin 1, 2, 4
ACS Applied Materials & Interfaces ( IF 8.3 ) Pub Date : 2024-05-05 , DOI: 10.1021/acsami.4c02594 Yihang Chen 1, 2 , Xiao Yang 1, 2, 3 , Xiaotong Fan 1, 2 , Ao Kang 1, 2 , Xuemin Kong 1, 2 , Guolong Chen 1, 2 , Chenming Zhong 1, 2 , Yijun Lu 1, 2, 4 , Yi Fan 2, 5 , Xu Hou 2, 4, 5 , Tingzhu Wu 1, 2, 4 , Zhong Chen 1, 2, 3, 4 , Shuli Wang 1, 2 , Yue Lin 1, 2, 4
Affiliation
Perovskite nanocrystal (PeNC) arrays are showing a promising future in the next generation of micro-light-emitting-diode (micro-LED) displays due to the narrow emission linewidth and adjustable peak wavelength. Electrohydrodynamic (EHD) inkjet printing, with merits of high resolution, uniformity, versatility, and cost-effectiveness, is among the competent candidates for constructing PeNC arrays. However, the fabrication of red light-emitting CsPbBrxI(3–x) nanocrystal arrays for micro-LED displays still faces challenges, such as low brightness and poor stability. This work proposes a design for a red PeNC colloidal ink that is specialized for the EHD inkjet printing of three-dimensional PeNC arrays with enhanced luminescence and stability as well as being adaptable to both rigid and flexible substrates. Made of a mixture of PeNCs, polymer polystyrene (PS), and a nonpolar xylene solvent, the PeNC colloidal ink enables precise control of array sizes and shapes, which facilitates on-demand micropillar construction. Additionally, the inclusion of PS significantly increases the brightness and environmental stability. By adopting this ink, the EHD printer successfully fabricated full-color 3D PeNC arrays with a spatial resolution over 2500 ppi. It shows the potential of the EHD inkjet printing strategy for high-resolution and robust PeNC color conversion layers for micro-LED displays.
中文翻译:
用于全彩 Micro-LED 显示器的三维钙钛矿纳米晶体阵列的电流体动力喷墨打印
由于窄发射线宽和可调峰值波长,钙钛矿纳米晶体(PeNC)阵列在下一代微发光二极管(micro-LED)显示器中展现出广阔的前景。电流体动力(EHD)喷墨打印具有高分辨率、均匀性、多功能性和成本效益的优点,是构建PeNC阵列的有力候选者之一。然而,用于Micro LED显示器的红光CsPbBr x I (3– x )纳米晶体阵列的制造仍然面临着亮度低和稳定性差等挑战。这项工作提出了一种红色 PeNC 胶体墨水的设计,专门用于三维 PeNC 阵列的 EHD 喷墨打印,具有增强的发光性和稳定性,并且适用于刚性和柔性基材。 PeNC 胶体墨水由 PeNC、聚合物聚苯乙烯 (PS) 和非极性二甲苯溶剂的混合物制成,能够精确控制阵列尺寸和形状,从而有利于按需构建微柱。此外,PS 的加入显着提高了亮度和环境稳定性。通过采用这种墨水,EHD打印机成功制造了空间分辨率超过2500 ppi的全彩3D PeNC阵列。它展示了 EHD 喷墨打印策略在 Micro-LED 显示器高分辨率和稳健的 PeNC 颜色转换层方面的潜力。
更新日期:2024-05-05
中文翻译:
用于全彩 Micro-LED 显示器的三维钙钛矿纳米晶体阵列的电流体动力喷墨打印
由于窄发射线宽和可调峰值波长,钙钛矿纳米晶体(PeNC)阵列在下一代微发光二极管(micro-LED)显示器中展现出广阔的前景。电流体动力(EHD)喷墨打印具有高分辨率、均匀性、多功能性和成本效益的优点,是构建PeNC阵列的有力候选者之一。然而,用于Micro LED显示器的红光CsPbBr x I (3– x )纳米晶体阵列的制造仍然面临着亮度低和稳定性差等挑战。这项工作提出了一种红色 PeNC 胶体墨水的设计,专门用于三维 PeNC 阵列的 EHD 喷墨打印,具有增强的发光性和稳定性,并且适用于刚性和柔性基材。 PeNC 胶体墨水由 PeNC、聚合物聚苯乙烯 (PS) 和非极性二甲苯溶剂的混合物制成,能够精确控制阵列尺寸和形状,从而有利于按需构建微柱。此外,PS 的加入显着提高了亮度和环境稳定性。通过采用这种墨水,EHD打印机成功制造了空间分辨率超过2500 ppi的全彩3D PeNC阵列。它展示了 EHD 喷墨打印策略在 Micro-LED 显示器高分辨率和稳健的 PeNC 颜色转换层方面的潜力。