β-Phenethylamine Synthesis: N-Pyridinium Aziridines as Latent Dual Electrophiles,Angewandte Chemie International Edition

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β-Phenethylamine Synthesis: N-Pyridinium Aziridines as Latent Dual Electrophiles
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-05-03 , DOI: 10.1002/anie.202406335
Samya Samanta ₁ , Promita Biswas ₁ , Braeden C O'Bannon ₁ , David C Powers ₁

Affiliation

N-pyridinium aziridines serve as latent dual electrophiles for the synthesis of β-phenethylamines. Ni-catalyzed aziridine ring opening with organozinc nucleophiles affords a diverse family of β-functionalized phenethylaminopyridinium salts which upon reductive N−N cleavage provides access to rapid and modular molecular assembly of β-phenethylamines.

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