In this issue of Chem Catalysis, He and co-workers demonstrate easy access to diverse glycosyl boro-ketosides via a rare glycosylidene carbene intermediate. They use stable glycosylidene diaziridines as precursors for carbene generation, leading to products convertible into rare sugars and pharmaceutically interesting derivatives, such as tofogliflozin.

中文翻译：

---

通过实验室稳定的糖基二氮丙啶驯化糖基卡宾以获得硼酮苷

在本期《化学催化》中，他和同事证明了通过一种罕见的糖基卡宾中间体可以轻松获得多种糖基硼酮苷。他们使用稳定的糖亚基二氮丙啶作为卡宾生成的前体，从而将产品转化为稀有糖和药学上有趣的衍生物，例如托福格列净。