A Comprehensive Exploration of Polysulfides, From Synthesis Techniques to Diverse Applications and Future Frontiers,ACS Applied Polymer Materials

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A Comprehensive Exploration of Polysulfides, From Synthesis Techniques to Diverse Applications and Future Frontiers
ACS Applied Polymer Materials ( IF 4.4 ) Pub Date : 2024-04-04 , DOI: 10.1021/acsapm.4c00272
Riffat Amna ₁ , Saeed M. Alhassan ₁

Affiliation

The present review offers a concise overview of polysulfides, focusing on various techniques for synthesizing polymers with high sulfur content through direct elemental sulfur polymerization. These methodologies encompass condensation, ionic, and free radical polymerizations. Of particular interest is the extensively discussed free radical polymerization type known as inverse vulcanization. The report delves into the diverse applications of polysulfides, spanning areas such as lithium–sulfur batteries, self-healing materials, IR imaging technology, energy storage, controlled fertilizer, antimicrobial agents, oil spill remediation, water-soluble polymers, and separation science, specifically in metal removal from wastewater. Polysulfides showcase distinctive properties, including optical, thermo-responsive, mechanical, and electrochemical attributes. However, it is crucial to acknowledge that this field is not without its challenges. The review briefly explores the current challenges and potential future developments associated with polysulfides. Additionally, it provides a cursory examination of the role of simulations, modeling, and artificial intelligence in advancing the understanding and applications of polysulfides.

中文翻译：

多硫化物从合成技术到多样化应用和未来前沿的全面探索

本综述对多硫化物进行了简要概述，重点介绍了通过直接元素硫聚合合成高硫含量聚合物的各种技术。这些方法包括缩合聚合、离子聚合和自由基聚合。特别令人感兴趣的是广泛讨论的自由基聚合类型，称为反硫化。该报告深入探讨了多硫化物的多种应用，涵盖锂硫电池、自修复材料、红外成像技术、能源储存、受控肥料、抗菌剂、溢油修复、水溶性聚合物和分离科学等领域。特别是从废水中去除金属。多硫化物表现出独特的特性，包括光学、热响应、机械和电化学属性。然而，重要的是要承认这一领域并非没有挑战。该综述简要探讨了与多硫化物相关的当前挑战和潜在的未来发展。此外，它还粗略地考察了模拟、建模和人工智能在促进多硫化物的理解和应用方面的作用。

更新日期：2024-04-04

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