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Physio-chemical and biological Characterizations of 4 Bromo – 4'Chloro Benzylidene Aniline μ-crystals for Engineering Utilities
ECS Journal of Solid State Science and Technology ( IF 1.8 ) Pub Date : 2024-04-03 , DOI: 10.1149/2162-8777/ad37d7
Balamurugapandian N , SenthilKannan K , Swarnalatha V , Juliet Josephine Joy J

4 Bromo—4’Chloro Benzylidene Aniline - as per suggestion it is named as 4B4CBA; Schiff based organic material has been synthesized and successfully grown by slow solvent evaporation technique. The orthorhombic crystal system of the grown crystal with space group Pccn is confirmed and cell parameters of the grown crystal of 4B4CBA is found by single crystal X-ray diffraction (XRD) analysis. The forming of the C-Cl and C-Br stretching vibrations at 719 cm−1 and 538 cm−1 in Fourier Transform Infra-Red (FTIR) study reveal the confirmation of 4B4CBA compound. The CHNSO analysis shows the presence of element in the 4B4CBA. The lower cutoff wavelength and wide optical absorption window of 4B4CBA exhibit the suitability of the present material for the projective opto-electronic applications. Nonlinear optical efficiency for different micro-crystalline of 4B4CBA is determined by second harmonic generation (SHG) experiment and is also compared with Potassium Dihydrogen Phosphate - KDP material. The electrical studies confirm that the 4B4CBA crystal possess low dielectric constant values at high frequency region. The experiment of photo-conductivity confirms the nature of the photo-conductivity of 4B4CBA crystal. The Scanning electron microscopy (SEM) analysis reveals the morphology of 4B4CBA crystal.

中文翻译:

用于工程公用事业的 4 溴 – 4'氯亚苄基苯胺 μ 晶体的物理化学和生物学表征

4溴—4'氯亚苄基苯胺——建议命名为4B4CBA;席夫基有机材料已通过缓慢溶剂蒸发技术合成并成功生长。确定了生长晶体的空间群为Pccn的斜方晶系,并通过单晶X射线衍射(XRD)分析找到了4B4CBA生长晶体的晶胞参数。傅里叶变换红外(FTIR)研究中719 cm -1和538 cm -1处C-Cl和C-Br伸缩振动的形成揭示了4B4CBA化合物的确认。 CHNSO 分析表明 4B4CBA 中存在元素。 4B4CBA 的较低截止波长和较宽的光学吸收窗口表明该材料适用于投影光电应用。通过二次谐波发生(SHG)实验确定了4B4CBA不同微晶的非线性光学效率,并与磷酸二氢钾-KDP材料进行了比较。电学研究证实 4B4CBA 晶体在高频区域具有低介电常数值。光电导实验证实了4B4CBA晶体的光电导性质。扫描电子显微镜 (SEM) 分析揭示了 4B4CBA 晶体的形貌。
更新日期:2024-04-03
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