Direct S0 → Tn Transition under Visible Light Irradiation Enabling Synthesis of a Pseudoindoxyl Scaffold,Organic Letters

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Direct S0 → Tn Transition under Visible Light Irradiation Enabling Synthesis of a Pseudoindoxyl Scaffold
Organic Letters ( IF 4.9 ) Pub Date : 2024-04-03 , DOI: 10.1021/acs.orglett.4c00957
Masaya Nakajima _{1,

2} , Sho Nagasawa ₁ , Keita Yamazaki ₁ , Tomohiro Yazawa ₁ , Honoka Yoneyama ₁ , Yuko Kotaka ₁ , Tetsuhiro Nemoto ₁

Affiliation

Pseudoindoxyl is a partial skeleton found in various natural products. Its light-absorption properties make it useful for the design of functional molecules. However, versatile synthesis methods have not yet been reported. In this report, we present a versatile synthetic method for pseudoindoxyls using the direct S₀ → T_n transition under visible light irradiation. We also discuss the application of pseudoindoxyls as photocatalysts.

中文翻译：

可见光照射下的直接 S0 → Tn 转变使得能够合成假吲哚酚支架

假吲哚酚是在各种天然产物中发现的部分骨架。其光吸收特性使其可用于功能分子的设计。然而，通用的合成方法尚未见报道。在本报告中，我们提出了一种在可见光照射下利用直接 S ₀ → T _n跃迁合成假吲哚酚的通用方法。我们还讨论了假吲哚酚作为光催化剂的应用。

更新日期：2024-04-03

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