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Vapor-Phase Synthesis of Poly(para-xylylene): From Coatings to Porous and Hierarchical Materials
Advanced Functional Materials ( IF 18.5 ) Pub Date : 2024-03-25 , DOI: 10.1002/adfm.202313511
Shu-Man Hu, Chin-Yun Lee, Theresia Cecylia Ramli, Jane Christy, Yu-Ming Chang, Kyung Jin Lee, Fang-Yu Chou, Yu-Chih Chiang, Hsien-Yeh Chen
Advanced Functional Materials ( IF 18.5 ) Pub Date : 2024-03-25 , DOI: 10.1002/adfm.202313511
Shu-Man Hu, Chin-Yun Lee, Theresia Cecylia Ramli, Jane Christy, Yu-Ming Chang, Kyung Jin Lee, Fang-Yu Chou, Yu-Chih Chiang, Hsien-Yeh Chen
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Poly(para-xylylene) (PPX) is a robust and biocompatible coating material that is widely used in various applications, including electronics, aerospace and defense materials, automotive materials, and biomaterials. In this progress report, recent developments in PPX technology ranging from the advancement of physical chemistry properties and structural properties for device integration to the transformation of 3D monolith materials of PPX with controls in outer and inner structures at the micro- and nanometer scales are highlighted. Based on emerging chemistry studies on [2.2]paracyclophanes, which are primarily used precursors to synthesize PPX via vapor deposition polymerization, functionalization, and the creation of a wide variety of functional PPX derivatives are demonstrated without resistance. Widely used as an interface coating material, PPX is processed to form integrated structural materials and has already been found to be useful in the market as part of electronic and medical implant products. Using a newly innovated transformation to fabricate PPX through templates (metal-organic frameworks, liquid crystal, ice crystal), 3D monoliths, nanoscale particles, hierarchical and gradient interior structures, and dynamically transformable shapes at the nanoscale are demonstrated. A vast landscape of novel applications and device products is expected based on the already established R&D and market maturity of PPX.
中文翻译:
聚对二甲苯的气相合成:从涂层到多孔和多级材料
聚对二甲苯 (PPX) 是一种坚固且具有生物相容性的涂层材料,广泛用于各种应用,包括电子、航空航天和国防材料、汽车材料和生物材料。在本进展报告中,重点介绍了 PPX 技术的最新发展,从用于器件集成的物理化学特性和结构特性的进步,到微米和纳米尺度上 PPX 的 3D 整体材料与外部和内部结构的控制转变。基于对 [2.2] 对环烷的新兴化学研究,[2.2] 对环烷主要用于通过气相沉积聚合合成 PPX,证明了官能化和产生多种功能性 PPX 衍生物是无阻力的。PPX 被广泛用作界面涂层材料,被加工成集成结构材料,并已被发现作为电子和医疗植入物产品的一部分在市场上有用。展示了使用新创新的转换通过模板(金属有机框架、液晶、冰晶)、3D 整体、纳米级颗粒、分层和梯度内部结构以及纳米级的动态可转换形状来制造 PPX。基于PPX已经建立的研发和市场成熟度,预计会有大量的新型应用和设备产品。
更新日期:2024-03-25
中文翻译:
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聚对二甲苯的气相合成:从涂层到多孔和多级材料
聚对二甲苯 (PPX) 是一种坚固且具有生物相容性的涂层材料,广泛用于各种应用,包括电子、航空航天和国防材料、汽车材料和生物材料。在本进展报告中,重点介绍了 PPX 技术的最新发展,从用于器件集成的物理化学特性和结构特性的进步,到微米和纳米尺度上 PPX 的 3D 整体材料与外部和内部结构的控制转变。基于对 [2.2] 对环烷的新兴化学研究,[2.2] 对环烷主要用于通过气相沉积聚合合成 PPX,证明了官能化和产生多种功能性 PPX 衍生物是无阻力的。PPX 被广泛用作界面涂层材料,被加工成集成结构材料,并已被发现作为电子和医疗植入物产品的一部分在市场上有用。展示了使用新创新的转换通过模板(金属有机框架、液晶、冰晶)、3D 整体、纳米级颗粒、分层和梯度内部结构以及纳米级的动态可转换形状来制造 PPX。基于PPX已经建立的研发和市场成熟度,预计会有大量的新型应用和设备产品。