Using readily available manganese pentacarbonyl bromide as a regeneration catalyst, biomimetic asymmetric reduction of imines including quinoxalinones, benzoxazinones, and benzoxazine has been successfully developed in the presence of transfer catalyst chiral phosphoric acids, providing the chiral amines with high yields and enantioselectivities.

中文翻译：

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五羰基溴化锰作为再生催化剂实现仿生不对称还原

使用易于获得的五羰基溴化锰作为再生催化剂，在转移催化剂手性磷酸存在下成功开发了包括喹喔啉酮、苯并恶嗪酮和苯并恶嗪在内的亚胺的仿生不对称还原，从而提供了高产率和对映选择性的手性胺。