Methyl (αE)-2-(bromomethyl)-α-(methoxyimino)benzeneacetate (MBMA), the key intermediate in the synthesis of Strobilurins fungicides, such as trifloxystrobin, kresoxim-methyl, fenaminstrobin, and dimoxystrobin, pose potential thermal safety risks. The thermal hazards of MBMA were investigated in this study. The thermal safety and decomposition kinetic parameters of MBMA were obtained, and the thermal decomposition mechanism and pyrolysis products of MBMA were analyzed using a combined test in conjunction with density functional theory (DFT), which is significant to understanding the intrinsic safety of MBMA in industry.

中文翻译：

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(αE)-2-(溴甲基)-α-(甲氧基亚氨基)苯乙酸甲酯的合成及热安全性评价

(αE)-2-(溴甲基)-α-(甲氧基亚氨基)苯乙酸甲酯(MBMA)是合成甲氧基丙烯酸酯类杀菌剂（例如肟菌酯、醚菌酯、芬胺肟酯、醚菌酯）的关键中间体，存在潜在的热安全风险。本研究调查了 MBMA 的热危害。获得了MBMA的热安全性和分解动力学参数，并结合密度泛函理论（DFT）联合测试分析了MBMA的热分解机理和热解产物，对于理解MBMA在工业上的本质安全性具有重要意义。