An iron-catalyzed nitrene transfer reaction of nitrosobenzenes with N-acyloxyamides for accessing N-acyl azoxy molecules,Organic Chemistry Frontiers

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An iron-catalyzed nitrene transfer reaction of nitrosobenzenes with N-acyloxyamides for accessing N-acyl azoxy molecules
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2024-03-06 , DOI: 10.1039/d4qo00137k
Weimin Huang ₁ , Haobo Yan ₁ , Qianqian Wang ₁ , Jianhui Chen ₁ , Yanshu Luo ₁ , Yuanzhi Xia ₁

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Reported herein is a nitrene transfer reaction of nitrosobenzenes with N-acyloxyamides using FeCl₂·4H₂O as a cheap and commercially available catalyst, affording N-acyl azoxy compounds with high functional-group compatibility. This facile transformation could be carried out smoothly under an air atmosphere at the gram scale and its synthetic utility was demonstrated by efficient reduction and aryl transfer reactions of the product.

中文翻译：

亚硝基苯与 N-酰氧基酰胺的铁催化氮烯转移反应，以获取 N-酰基偶氮氧基分子

本文报道了亚硝基苯与N-酰氧基酰胺的氮宾转移反应，使用FeCl ₂ ·4H ₂ O作为廉价且市售的催化剂，提供具有高官能团相容性的N-酰基偶氮氧基化合物。这种简便的转化可以在克级的空气气氛下顺利进行，并且通过产物的有效还原和芳基转移反应证明了其合成实用性。

更新日期：2024-03-06

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