Synthesis of Bicyclo[1.1.1]pentane Carboxamides and Ketones from [1.1.1]Propellane,European Journal of Organic Chemistry

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Synthesis of Bicyclo[1.1.1]pentane Carboxamides and Ketones from [1.1.1]Propellane
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2024-03-03 , DOI: 10.1002/ejoc.202301297
Min Ling ₁ , Mengke Chen ₁ , Qian Jiang ₁ , dongping cheng ₂ , Jing-Hua Li ₃

Affiliation

A convenient method for acylation of [1.1.1]propellane to give bicyclo[1.1.1]pentane (BCP) carboxamides and ketones has been developed. It provides a straightforward one-step access to monosubstituted BCP carboxamides, synthesis of which requires multiple chemical steps in previous reports.

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