A Chiral [2+3] Covalent Organic Cage Based on 1,1’-Bi-2-naphthol (BINOL) Units,Chemistry - A European Journal

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A Chiral [2+3] Covalent Organic Cage Based on 1,1’-Bi-2-naphthol (BINOL) Units
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2024-03-01 , DOI: 10.1002/chem.202400458
Midhun Mohan ₁ , David-Jérôme Pham ₁ , Audrey Fluck ₁ , Simon Chapuis ₂ , Alain Chaumont ₂ , Brice Kauffmann ₃ , Laurent Barloy ₁ , Pierre Mobian ₁

Affiliation

A chiral cage formed with three 2,2’-BINOL units was prepared through a dynamic covalent chemistry approach. This architecture contains six OH functions pointing inside the cavity. Host-guest studies demonstrated enantiopreference of the cage for a chiral ammonium cation.

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