A Conjugated Phenylene Nanocage with a Guest-Adaptive Deformable Cavity,Angewandte Chemie International Edition

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A Conjugated Phenylene Nanocage with a Guest-Adaptive Deformable Cavity
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-02-29 , DOI: 10.1002/anie.202403062
Jingxuan Yang _{1,

2} , Liang-Liang Mao ₁ , Hongyan Xiao ₃ , Guohui Zhang ₄ , Shaoguang Zhang ₄ , Lei Kang _{2,

5} , Zheshuai Lin _{2,

5} , Chen-Ho Tung _{1,

2} , Li-Zhu Wu _{1,

2} , Huan Cong _{1,

2}

Affiliation

A conjugated phenylene nanocage featuring a highly deformable cavity has been constructed from a pliable calix[6]arene moiety and a strained phenylene moiety. The cage contains a guest-adaptive cavity, the volume of which can expand by as much as 85 % upon complexation with fullerene guests of different sizes.

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