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A Novel Homoconjugated Propellane Triimide: Synthesis, Structural Analyses, and Gas Separation
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-02-28 , DOI: 10.1002/anie.202401706 Yan Chen 1 , Yongting Zhao 1 , Yubo Zhao 1 , Xiangping Chen 1 , Xinyue Liu 1 , Lin Li 2 , Dapeng Cao 1 , Shitao Wang 1 , Lei Zhang 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2024-02-28 , DOI: 10.1002/anie.202401706 Yan Chen 1 , Yongting Zhao 1 , Yubo Zhao 1 , Xiangping Chen 1 , Xinyue Liu 1 , Lin Li 2 , Dapeng Cao 1 , Shitao Wang 1 , Lei Zhang 1
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A novel homoconjugated propellane comprising three imide groups embedded on a trinaphtho[3.3.3]propellane, has been synthesized and characterized. This rigid propellane triimide is featured with large bathochromic shift, intense luminescence, amplified molar absorptivity, and lower reduction potential relative to the subunits. The propellane triimide readily crystallizes into porous 3D superstructure, which is promising for C2H6/C2H4 separation.
中文翻译：
新型均共轭丙烷三酰亚胺：合成、结构分析和气体分离
已经合成并表征了一种新型均共轭丙烷，其包含嵌入三萘并[3.3.3]丙烷上的三个酰亚胺基团。这种刚性的丙烷三酰亚胺具有大的红移、强烈的发光、放大的摩尔吸收率以及相对于亚基较低的还原电位。丙烷三酰亚胺很容易结晶成多孔3D超结构，这对于C 2 H 6 /C 2 H 4分离很有希望。
更新日期：2024-02-28
中文翻译：
新型均共轭丙烷三酰亚胺：合成、结构分析和气体分离
已经合成并表征了一种新型均共轭丙烷，其包含嵌入三萘并[3.3.3]丙烷上的三个酰亚胺基团。这种刚性的丙烷三酰亚胺具有大的红移、强烈的发光、放大的摩尔吸收率以及相对于亚基较低的还原电位。丙烷三酰亚胺很容易结晶成多孔3D超结构，这对于C 2 H 6 /C 2 H 4分离很有希望。
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