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Decarboxylative C–N Coupling of 2,2-Difluorobicyclo[1.1.1]pentane (BCP-F2) Building Blocks
Organic Letters ( IF 4.9 ) Pub Date : 2024-02-22 , DOI: 10.1021/acs.orglett.4c00307 Xiaoshen Ma 1 , Joanna L Chen 1 , Bryce E Gaskins 1
Organic Letters ( IF 4.9 ) Pub Date : 2024-02-22 , DOI: 10.1021/acs.orglett.4c00307 Xiaoshen Ma 1 , Joanna L Chen 1 , Bryce E Gaskins 1
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Described herein is our effort toward achieving the decarboxylative functionalization of 2,2-difluorobicyclo[1.1.1]pentane (BCP-F2) building blocks. When compared with the nonfluorinated bicyclo[1.1.1]pentane (BCP) analogues, we discovered divergent reactivities. This is the first successful decarboxylative coupling of BCP-F2 building blocks reported via the photoredox mechanism.
中文翻译:
2,2-二氟双环[1.1.1]戊烷 (BCP-F2) 结构单元的脱羧 C-N 偶联
本文描述的是我们为实现 2,2-二氟双环[1.1.1]戊烷 (BCP-F 2 ) 结构单元的脱羧官能化所做的努力。与非氟化双环[1.1.1]戊烷(BCP)类似物相比,我们发现了不同的反应性。这是通过光氧化还原机制报道的第一个成功的 BCP-F 2结构单元的脱羧偶联。
更新日期:2024-02-22
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
2,2-二氟双环[1.1.1]戊烷 (BCP-F2) 结构单元的脱羧 C-N 偶联
本文描述的是我们为实现 2,2-二氟双环[1.1.1]戊烷 (BCP-F 2 ) 结构单元的脱羧官能化所做的努力。与非氟化双环[1.1.1]戊烷(BCP)类似物相比,我们发现了不同的反应性。这是通过光氧化还原机制报道的第一个成功的 BCP-F 2结构单元的脱羧偶联。