Described herein is our effort toward achieving the decarboxylative functionalization of 2,2-difluorobicyclo[1.1.1]pentane (BCP-F₂) building blocks. When compared with the nonfluorinated bicyclo[1.1.1]pentane (BCP) analogues, we discovered divergent reactivities. This is the first successful decarboxylative coupling of BCP-F₂ building blocks reported via the photoredox mechanism.

中文翻译：

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2,2-二氟双环[1.1.1]戊烷 (BCP-F2) 结构单元的脱羧 C-N 偶联


本文描述的是我们为实现 2,2-二氟双环[1.1.1]戊烷 (BCP-F ₂ ) 结构单元的脱羧官能化所做的努力。与非氟化双环[1.1.1]戊烷（BCP）类似物相比，我们发现了不同的反应性。这是通过光氧化还原机制报道的第一个成功的 BCP-F ₂结构单元的脱羧偶联。