This study effectively synthesized thiazole-4-carbohydrazide (SZCA) and its ionic salt SZCA·HClO and energetic complex Cu(SZCA)(ClO) (). The new compound SZCA, SZCA·HClO and were fully characterized through elemental analysis, infrared spectroscopy, C NMR spectroscopy and thermal stability analysis. The combustion heat of was measured by oxygen bomb calorimetry, and its detonation performance was predicted by Kamlet-Jacobs formula and EXPLO5, respectively. The mechanical sensitivity of was tested using BAM method. In particular, we comprehensively evaluated the initiation ability of through lead plate destruction experiment and laser initiation experiment. The results show that have a decomposition temperature of 236 °C, exhibits acceptable mechanical sensitivity (impact sensitivity: 3.4 J, friction sensitivity: 4 N), and decent detonation properties (: 6.6 km s, : 21.3 GPa). And could be initiated by a single-pulse laser (λ: 808 nm, : 20 W, : 3 ms), and successfully detonated the next charge, such as RDX and CL-20.

中文翻译：

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一种基于噻唑-4-碳酰肼的新型含硫激光敏感起爆药


本研究有效合成了噻唑-4-碳酰肼（SZCA）及其离子盐SZCA·HClO和含能络合物Cu(SZCA)(ClO) ()。通过元素分析、红外光谱、核磁共振氢谱和热稳定性分析对新化合物SZCA、SZCA·HClO进行了充分表征。采用氧弹量热法测量其燃烧热，并分别采用Kamlet-Jacobs公式和EXPLO5预测其爆轰性能。采用BAM方法测试机械灵敏度。特别是通过铅板破坏实验和激光起爆实验综合评价了起爆能力。结果表明，其分解温度为 236 °C，具有可接受的机械灵敏度（冲击灵敏度：3.4 J，摩擦灵敏度：4 N）和良好的爆炸性能（6.6 km s，21.3 GPa）。并且可以通过单脉冲激光（λ：808 nm，：20 W，：3 ms）引发，并成功引爆下一个装药，例如RDX和CL-20。