Highly Stereoselective Olefin Cyclopropanation of Diazooxindoles Catalyzed by aC2-Symmetric Spiroketal Bisphosphine/Au(I) Complex,Journal of the American Chemical Society

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Highly Stereoselective Olefin Cyclopropanation of Diazooxindoles Catalyzed by aC2-Symmetric Spiroketal Bisphosphine/Au(I) Complex
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2013-05-24 , DOI: 10.1021/ja4040895
Zhong-Yan Cao ₁ , Xiaoming Wang ₂ , Chen Tan ₁ , Xiao-Li Zhao ₁ , Jian Zhou ₁ , Kuiling Ding ₂

Affiliation

A spiroketal bisphosphine (SKP) derived chiral digold complex is identified as a powerful catalyst for the highly diastereo- and enantioselective synthesis of spirocyclopropyloxindoles from diazooxindoles and a broad range of alkenes, including both cis and trans 1,2-disubstituted alkenes.

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